Functional Groups

Functional Groups MDCAT MCQs with answers

7 past paper MCQs on Functional Groups, from the Fundamental Principles of Organic Chemistry unit of MDCAT Chemistry. The year each question appeared is shown where known; tap “Show answer” for the correct option and a short solution.

1.The compounds containing the $\mathrm{R-SH}$ functional group are known as: (MDCAT 2022)

  1. alcohols
  2. thio-alcohols
  3. thio-ethers
  4. nitriles
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Correct answer: (b) thio-alcohols

Sulphur in the place of the oxygen of an alcohol gives a thio-alcohol, or thiol.

2.CnH2nO is the general formula of: (UHS MDCAT 2024)

  1. Ether
  2. Carboxylic acid
  3. Ketones
  4. Carbolic acid
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Correct answer: (c) Ketones

A ketone of formula $\mathrm{C_nH_{2n}O}$ carries one carbonyl group inside the chain.

3.Name of ketone functional group is (KMU MDCAT 2024)

  1. Amino
  2. Carbonyl
  3. Carboxyl
  4. Formyl
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Correct answer: (b) Carbonyl

The group in a ketone is the carbonyl group.

4.In which of the following functional groups, the carbon atom is sp hybridized? (UHS MDCAT 2023)

  1. -CHO
  2. -COOH
  3. -CN
  4. -COOR
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Correct answer: (c) -CN

The carbon of a nitrile is triply bonded to nitrogen, so it is sp hybridized.

5.The compounds containing R-SH functional group are known as: (UHS MDCAT 2023)

  1. Alcohols
  2. Thio-alcohols
  3. Thio-ether
  4. Nitrile
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Correct answer: (b) Thio-alcohols

Replacing the oxygen of an alcohol with sulphur gives a thio-alcohol, or thiol.

6.Which of the functional group are present in ethyl acetate? (UHS MDCAT 2023)

  1. Aldehyde group
  2. Carboxyl group
  3. Ester group
  4. Ether group
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Correct answer: (c) Ester group

Ethyl acetate is the ester of acetic acid and ethanol.

7.Which of the following is an oxonium ion? (PMC MDCAT 2022)

  1. NH4+
  2. PH4+
  3. RSH2+
  4. H3O+
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Correct answer: (d) H3O+

The hydronium ion is an oxonium ion, oxygen with three bonds and a positive charge.

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